Product ID:HANDI-CRETE CONCRETE 1141
MSDS Date:08/01/1998
FSC:NIIN:Submitter:N EN
Status Code:A
MSDS Number: CJYPQ

QUIKRETE COMPANIES

2987 CLAIRMONT ROAD SUITE 500
ATLANTA, GA 30329
US

Emergency Phone: 770-216-9580

Info Phone: 770-216-9580

Preparer: DUANE L SMITH

Cage: QUTKB

QUIKRETE COMPANIES

ATLANTA, GA 30329 US

Telephone: 770-216-9580

Cage: QUTKB

QUARTZ; (SILICA SAND, CRYSTALLINE)

CAS: 14808-60-7

RTECS: VV7330000

OSHA PEL see Table Z-3

ACGIH TLV: 0.1 MG/M3

CEMENT, PORTLAND, CHEMICALS; (PORTLAND CEMENT)

CAS: 65997-15-1

RTECS: VV8770000

OSHA PEL 15 MG/M3

ACGIH TLV: 10 MG/M3

LIME (CHEMICAL), SLAKED OR HYDRATED; (LIME)

CAS: 1305-62-0

RTECS: EW2800000

OSHA PEL 15 MG/M3

ACGIH TLV: 5 MG/M3

SILICA; (AMORPHOUS SILICA (FROM FLY ASH)

CAS: 7631-86-9

RTECS: VV7565000

ALUMINA; (ALUMINA (FROM FLY ASH)

CAS: 1344-28-1

RTECS: BD1200000

OSHA PEL 15 MG/M3

ACGIH TLV: 10 MG/M3

LIMESTONE; (LIMESTONE DUST)

CAS: 1317-65-3

RTECS: EV9580000

OSHA PEL 15 MG/M3

ACGIH TLV: 10 MG/M3

CALCIUM SULFATE DIHYDRATE; (CALCIUM SULFATE) MFR ALTERNATE

CAS: 10101-41-4

RTECS: EW4150000

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: PROD BECOMES ALKALINE WHEN
EXPOSED TO MOISTURE. EXPOS CAN DRY SKIN, CAUSE ALKALI BURNS & EFT
MUC MEMS. DUST CAN IRRIT EYES & UPPER RESP SYS. TOX EFTS NOTED IN
ANIMALS INCL, FOR ACUTE EXPOS, ALV EOLAR DMG W/PULM EDEMA. CHRONIC:
DUST CAN CAUSE INFLAMM OF LINING TISS OF INTERIOR OF NOSE & INFLAMM
OF CORNEA. HYPERSENS INDIVIDUALS MAY DEVELOP ALLERGIC DERM.
RESPIRABLE CRYSTALLINE SILICA (QUARTZ) CAN CAUSE SILICOSIS,
FIBROSIS (SCARRING) OF LUNGS & POSSIBLY CANCER. THERE IS EVIDENCE
THAT EFTS OF EXPOS TO RESPIRABLE SILICA/DISEASE SILICOSIS IS
ASSOCD W/INCR INCIDENCE OF SCLERODERMA, TUBERCULOSI S & KIDNEY
DISORDERS. (EFTS OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE - QUARTZ: IARC
MONOGRAPHS VOLUME 68, PAGE 41, 1997: GROUP 1. NTP 8TH ANNUAL REPORT
ON CARCINOGENS, 1998: REASONABLY ANTICIPATED TO BE CARCINOGEN.
Effects of Overexposure:HLTH HAZ: SIGNS & SYMPS OF EXPOS: SYMPS OF
EXCESSIVE EXPOS TO DUST INCL SHORTNESS OF BRTH & REDUCED PULM
FUNCTION. EXCESSIVE EXPOS TO SKIN & EYES ESP WHEN MIXED W/H*2O CAN
CAUSE CAUSTIC BURNS AS SEV A S THIRD DEGREE. NTP: THE NTP PROGRAM,
IN ITS 6TH ANNUAL RPT ON CARCIN CONCLUDED THAT "SILICA, CRYSTALLINE
(RESPIRABLE)" MAY REASONABLY BE ANTICIPATED TO BE CARCIN, BASED ON
SUFFICIENT EVID IN EXPERIME NTAL ANIMALS & LIMITED EVID IN HUMANS.
IARC: THE IARC CONCLUDED THAT THERE WAS "SUFFICIENT EVID IN HUMANS
FOR CARCIN OF CRYSTALLINE SILICA IN FORMS OF QUARTZ/CRISTOBALITE"
FROM OCCUP SOURCES", (SUPDA T)
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH SENSITIVE SKIN AND
WITH PULMONARY AND/OR RESPIRATORY DISEASE, INCLUDING, BUT NOT
LIMITED TO, ASTHMA AND BRONCHITIS, OR SUBJECT TO EYE IRRITATION,
SHOULD BE PRECLUDED FROM EXPOSURE.

First Aid:EYES: IRRIGATE (FLOOD ) EYES IMMEDIATELY AND REPEATEDLY WITH
CLEAN WATER FOR AT LEAST 15 MINUTES. SKIN: WASH EXPOSED SKIN AREAS
WITH SOAP AND WATER. IF IRRITATION OR INFLAMMATION OCCURS SEEK
PROMPT ME DICAL ATTENTION. INHALATION: FOR GROSS INHALATION,
REMOVE PERSON IMMEDIATELY TO FRESH AIR, GIVE ARTIFICIAL RESPIRATION
AS NEEDED. GET PROMPT MEDICAL ATTENTION. INGESTION: CALL MD
IMMEDIATELY .

Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NON COMBUSTIBLE AND NOT EXPLOSIVE.

Spill Release Procedures:IF SPILLED, USE DUSTLESS METHODS (VACUUM) AND
PLACE INTO CLOSABLE CONTAINER FOR DISPOSAL OR USE IF NOT
CONTAMINATED OR WET. USE ADEQUATE VENTILATION.

Handling and Storage Precautions:WARN EMPLOYEES AND/OR CUSTOMERS OF THE
HAZARDS AND REQUIRED OSHA PRECAUTIONS ASSOCIATED WITH THE USE OF
THIS PRODUCT.
Other Precautions:PRECAUTIONS MUST BE OBSERVED BECAUSE BURNS OCCUR WITH
LITTLE WARNING -- LITTLE HEAT IS SENSED.

Respiratory Protection:DO NOT BREATHE DUST. IN DUSTY INVIRONMENTS, THE
USE OF NIOSH APPROVED RESPIRATOR IS RECOMMENDED.
Ventilation:LOCAL EXHAUST CAN BE USED, IF NECESSARY, TO CONTROL
AIRBORNE DUST LEVELS.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . USE OF BARRIER CREAMS, BOOTS AND CLOTHING TO
PROTECT THE SKIN FROM CONTACT IS RECOMENDED.
Work Hygienic Practices:FOLLOWING WORK, WORKERS SHOULD SHOWER WITH SOAP
AND WATER.
Supplemental Safety and Health
EFTS OF OVEREXP: & THAT THERE IS "SUFFICIENT EVID IN EXPERIMENTAL
ANIMALS FOR CARCIN OF QUARTZ/CRISTOBALITE." OVERALL IARC EVALUATION
WAS THAT "CRYSTALLINE SILICA INHALED IN FORM OF QUARTZ/CRISTOBALI
TE FROM OCCUP SOURCES IS CARCIN TO HUMANS (GROUP 1)." IARC
EVALUATION NOTED THAT "CARCIN WAS NOT (OTHER INFO)

Boiling Pt:>1482.2C, 2700.F
Melt/Freeze Pt:>1482.2C, ######F
Vapor Pres:NONE
Vapor Density:NONE
Spec Gravity:2.6 - 3.15
Evaporation Rate & Reference:NONE
Solubility in Water:SLIGHT
Appearance and Odor:GRAY TO GRAY-BROWN COLORED POWDER. SOME PRODUCTS
CONTAIN COARSE (OTHER INFO)

Stability Indicator/Materials to Avoid:YES
CONTACT OF SILICA WITH POWERFUL OXIDIZING AGENTS SUCH AS FLUORINE,
CHLORINE TRIFLUORIDE, MANGANESE TRIOXIDE, OXYGEN DIFLUORIDE, MAY
CAUSE FIRES.
Stability Condition to Avoid:KEEP DRY UNTIL USED TO PRESERVE PRODUCT
UTILITY.
Hazardous Decomposition Products:SILICA WILL DISSOLVE IN HYDROFLUORIC
ACID AND PRODUCE A CORROSIVE GAS-SILICON TETRAFLUORIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:THE PACKAGING AND MATERIAL MAY BE LAND FILLED;
HOWEVER, MATERIALS SHOULD BE COVERED TO MINIMIZE GENERATION OF
AIRBORNE DUST. THIS PRODUCT IS NOT CLASSIFIED AS A HAZARDOUS WASTE
UNDER RCRA OR CERCLA.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NO DATA AVAILABLE.

Transport Information:U.S. DEPARTMENT OF TRANSPORTATION: PROPER
SHIPPING NAME: COMBUSTIBLE LIQUID, N.O.S. (CONTAINS HYDROTREATED
LIGHT PETROLEUM DISTILLATES), NA 1993, PG I I I. FOR BULK SHIPMENT
ONLY. D.O.T. HAZARD CLASS: COMBUSTIBLE LIQUID. UN/NA ID NUMBER: NA
1993. EMERGENCY RESPONSE GUIDE NUMBER: ERG: # 27 (1993). ERG # 128
(1996).

SARA Title III Information:THIS PRODUCT DOES NOT CONTAIN ANY MATERIAL
WHICH IS SUBJECT TO THE ANNUAL REPORTING REQUIREMENTS UNDER SECTION
313 OF SARA, TITLE I I I. CONTACT THE EPA FOR INFORMATION REGARDING
THE REPORTING REQUIRE MENTS. THIS PRODUCT HAS BEEN REVIEWED IN
ACCORDANCE WITH SECTION 311 (MSDS INVENTORY) AND SECTION 312 (TIER
I / I I INVENTORY) OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (CFR 40 370.2 ) FOR "HAZARD CATEGORY" STATUS. UNDER
APPLICABLE DEFINITIONS, THIS PRODUCT MEETS THE FOLLOWING
CATEGORIES: IMMEDIATE (ACUTE) HEALTH HAZARD, DELAYED (CHRONIC)
HEALTH HAZARD, AND FIRE HAZARD.
Federal Regulatory Information:TOXIC SUBSTANCE CONTROL ACT (TSCA): THIS
PRODUCT AND/OR ALL INGREDIENTS CONTAINED IN THIS PRODUCT HAVE BEEN
REGISTERED UNDER THE TOXIC SUBSTANCE CONTROL ACT. R.C.R.A.: THIS
PRODUCT DOES NOT MEET THE D EFINITIONS OR CONTAIN ANY SUBSTANCE
APPEARING IN THE LISTINGS CONTAINED IN 40CFR261, "IDENTIFICATION
AND LISTING OF HAZARDOUS WASTE." THIS PRODUCT DOES NOT CONTAIN OR
WAS NOT MANUFACTURED WITH ANY OF THE EPA CLASS I OR CLASS I I
OZONE DEPLETING SUBSTANCES.
State Regulatory Information:NOT PROVIDED